Removal of Ni ions from aqueous solutions using melamine-modified nano graphene oxide adsorbent

Document Type : Research Paper

Authors

1 Master of Science in Environmental Engineering, Environmental Pollution, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran

2 Associate Professor, Department of Environment, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran

Abstract

Heavy metal pollutions is one of the problems that is danderous for human and the environment. Environmental pollutants such as heavy metals, when enter the human body through nutrition can damage various parts of the body such as the cardiovascular system, lungs, liver, and kidneys, and cause dangerous effects. Industrial sewage contains heavy metals such as nickel, lead, copper, zinc, and cadmium. In the present research, melamine-modified nanographene oxide was used. to investigate and identify melamine-modified nano-graphene oxide, the field emission microscope (FESEM), the Tensor Fourier transform infrared spectroscopy (FTIR) and the X-ray diffraction (XRD) were used. In this study, effects of pH (2 -7), concentration (5-200) mg/g, absorbent dose (0.01-0.06) g, temperature (15-50) °C and Contact time (15 to 150) minutes was investigated on the adsorption process To determine the adsorption mechanism, thermodynamics, pseudo first and second-order kinetics, and Freundlich and Langmuir adsorption isotherms on the adsorption process were performed. Nickel metal concentration was measured by atomic absorption spectrometry.The results showed that the adsorption rate is consistent with the Freundlich isotherm model and the pseudo-second-order kinetic equation.Thermodynamic studies also showed that the adsorption process is associated with increasing irregularities and is endothermi. highest absorption rate at a concentration of 200 mg /l, highest percentage of removal occurs in 150 minutes, which is equal to 1915/75 mg/g and 99/825%,respectively. Based on the results, melamine-modified nanographene oxide can be used as a suitable adsorbent to remove nickel from aqueous environments due to its high adsorption capacity and convenient and cost-effective performance

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Main Subjects


Akbari, A., Allah Qoli Qasri, M., and Mohammad Ali Tehrani, R. 2015. Synthesis and characterization of nanocomposite nanoparticles of nanotubes / graphene oxide to remove lead from the environment. Applied Research in Chemistry. 8(4), 25-33. (in Persian)
Balati, A., Shahbazi, A., Amini, M.M., Hashemi, SH., and Jadidi, K. 2014. Comparison of the efficiency of mesoporous silicas as absorbents for removing naphthalene from contaminated water. European Journal of Environmental Sciences.4(1),69-76.
Barati, F.,bahrebar, F., and bahrebar, F. 2017. Investigation of the effect of initial concentration by adsorption method on lead removal using graphene adsorbent. 4th National Congress of Biology and Natural Sciences of Iran: Mehr Arvand Higher Education Institute - Center for Strategies for Achieving Sustainable Development. (in Persian).
Cao, A., Liu, Z., Chu, S., Wu, M., Ye, Z., and Cai, Z. 2010.A facile one‐step method to produce graphene–CdS quantum dot nanocomposites as promising optoelectronic materials. Advanced materials. 22(1),103-106.
Davarpanah, R., Tabatabai Ghomsheh, S., Jahantab, Z., and Bahreh bar, A. 2014. effect of contact time on nickel removal by adsorption method using graphene adsorbent. 2nd National Conference on Environment, Energy and Environmental Defense: Mehr Arvand Higher Education Institute. (in Persian)
El-Sadaawy, M., and Abdelwahab, O. 2014. Adsorptive removal of nickel from aqueous solutions by activated carbons from doum seed (Hyphaenethebaica) coat. Alexandria Engineering Journal. 53(2),399-408
Fan, H.L., Zhou, S.F., Jiao, W.Z., Qi, G.S., and Liu, Y.Z. 2017. Removal of heavy metal ions by magnetic chitosan nanoparticles prepared continuously via high-gravity reactive precipitation method. Carbohydrate Polymers. 174, 1192–1200.
Gharebiglou, M., Izadkhah, MS., Erfan-Niya, H., and Entezami, AA. 2016. Improving the mechanical and thermal properties of chemically modified graphene oxide/polypropylene nanocomposite. Modares Mechanical Engineering. 16(8),196-206.
Ghasemi, N., Ghasemi, M., Wan Alavi, SR., and Abdul Manan, Z. 2013. Removal of Nickel (II) from aqueous solution by activated carbon prepared from Askari grape dust. Proceedings of the 6th international conference on process  systems engineering (PSE ASIA). 25-27: kuala Lumpour, Malaysia
Iram, M., Guo, C., Guan, Y., Ishfaq, A., and Liu, H. 2010. Adsorption and magnetic removal of neutral red dye from aqueous solution using Fe3O4 hollow nanospheres. Journal of Hazardous Materials. 181(1),1039-1050.
Jamali, HA., Dindarloo, K., and Nikpey, A. 2015. Optimization of metal working fluids treatment using Ferric chloride by application of response surface methodology (RSM). Journal of Preventive Medicine. 2(1), 10-20. (in Persian).
Kakavandi, B., Jonidi, A., Rezaei, R., Nasseri, S., Ameri, A., and Esrafily, A. 2013. Synthesis and properties of Fe 3 O 4-activated carbon magnetic nanoparticles for removal of aniline from aqueous solution: equilibrium, kinetic and thermodynamic studies. Iranian Journal of Environmental Health Science and Engineering. 10(1),19.
Leyva Ramos, R., Fuentes Rubio, L., Guerrero Coronado, RM., and Mendoza Barron, J. 1995. Adsorption of trivalent chromium from aqueous solutions onto activated carbon. Journal of Chemical Technology and Biotechnology. 62(1),64-67.
Mahvi, A.H., and Heibati, B. 2011. removal efficiency of azo dyes from textile effluent using activated carbon made from walnut wood and determination of isotherms of acid red18.  Journal of Health and Hygiene.1 (3),7-15. (in Persian)
Mohammadnia, A., Hadavi Far, M., and Wesi, H.2017. Functionalization of graphene oxide nanoparticles to remove heavy metals from aqueous media. Fourth International Conference on Applied Research in Chemistry and Biology. (in Persian)
Mohan, D., Singh, KP., and Singh, VK. 2006. Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth. Journal of Hazardous Materials. 135(1-3),280-295
Mukherjee, AB. 1998. Nickel: a review of occurrence, uses, emissions,and concentration in the environment in Finland. Environmental Review. 6(1),1-15.
Naghizadeh, A., and Momeni, F. 2015.  Evaluation of graphen oxide nanoparticles efficacy in chromium and lead removal from aqueous solutions  journal of birjand university of medical sciences. 22 (1), 27-38 (in Persian).
Nujić, M, 2019. Toxic Metal Ions in Drinking Water and Effective Removal Using Graphene Oxide Nanocomposite. In: Naushad M, editor. A New Generation Material Graphene: Applications in Water Technology. Springer International Publishing. p. 373-395.
Quintelas, C., Rocha, Z., Silva, B., Fonseca, B., Figure ueiredo, H., andTavares, T. 2009. Biosorptive performance of an Escherichia coli biofilm supported on zeolite NaY for the removal of Cr (VI), Cd (II), Fe (III) and Ni (II). Chemical Engineering Journal.152(1),110-115
Rezaei, H. 2016. Biosorption of chromium by using Spirulina sp. Arabian Journal of Chemistry. 9(6), 846-853
Salvato, J.A., Nemerow, N.L., and Agardy, F.J. 2003. Environmental engineering: Publisher. John Wiley & Sons. ISBN       0471418137, 9780471418139. Length:1544 pages
Turtureanu, A., Georgescu, C., and  Oprean, L. 2008. Nickel removal from aqueous solutions by flotation with cationic collector. Determination of the Optimum Separation Conditions. 53(67), 1-2
Wang, X., Guo, Y., Yang, LI., Han, M., Zhao, J., and Cheng, X. 2012. Nanomaterials as Sorbents to Remove Heavy Metal Ions in Wastewater Treatmen. Journal of Environmental and Analytical Toxicology. 2(7),154-158
White, C.M. 2015. Evaluating the Viability of Graphene Oxide for the Removal of Ni (II) Ions From Waste Water. Biomedical Engineering Undergraduate Honors Theses
Yakout, S.M., and Elsherif, E. 2010. Batch kinetics, isotherm and thermodynamic studies of adsorption of strontium from aqueous solutions onto low cost rice-straw based carbons.  Carbon - Science and Technology. 3(1),144-153
Zafarzadeh, A., Mehdinejad, M., and Amani N. 2015. Accumulation of Heavy Metals in Agricultural Soil Irrigated by Sewage Sludge and Industrial Effluent (Case Study: Agh ghallah Industrial Estate. Journal Mazandaran University Medical Science. 24 (121), 217-226. )in Persian)
Zazouli, MA., and Yousefi, Z. 2008. Removal of heavy metals from solid wastes leachates coagulation-flocculation process. Journal Applied Science. 8(11), 2142-2147.
Zhao, G., Li, J., Ren, X., Chen, C.,  and Wang X. 2011. Few-Layered Graphene Oxide Nanosheets As Superior Sorbents for Heavy Metal Ion Pollution Management. Environmental Science and Technology. 45(24),10454-10462.